Гібридні композити синтезовані при карбонізації ацетилацетону та ацетилацетонатів металів на поверхні силікагелю
Анотація
Гібридні адсорбенти з вуглецем/кремнеземом, вуглецем/оксидом металу/кремнеземом і вуглецем/металом/кремнеземом можуть бути цікаві з практичної точки зору, оскільки вони можуть ефективно адсорбувати як полярні, так і неполярні сполуки. Тому мезопористий силікагель Si–60, модифікований карбонізацією ацетилацетону або ацетилацетонатів цирконію, титану, нікелю, цинку, хрому та кобальту досліджували за допомогою адсорбції-десорбції азоту та води, термогравіметрії, трансмісійної електронної мікроскопії, рентгенівської дифракції та рентгенівської флуоресценції. Прищеплені фази C/X складаються із сполук металу (X позначає оксид або силікат металу або метал) і вугілля, характеристики яких можна змінювати, змінюючи метал у прекурсорах та їхню кількість при карбонізації. Морфологічні, структурні та текстурні характеристики C/X/SiO2, такі як склад і розподіл частинок за розміром депозитів, число та сорт полярних та неполярних поверхневих центрів, питома поверхня, об’єм пор та розподіл пор за розмірами залежать від типу і вмісту депозитів C/X. Зміни в прищеплених речовинах відбуваються зі збільшенням концентрації прекурсору та C/X та можливого каталітичного ефекту X-фаз на карбонізацію. Правильний підбір структури та кількості прекурсорів дозволяє контролювати характеристики гібридних адсорбентів, що важливо з практичної точки зору.
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